Passivation has a profound effect on the chromium/iron ratio in mechanically polished Type 316L tubing. This publication summarizes the effect of nitric acid passivation time on the surface chemistry of polished sanitary tube.
X-ray photoelectron spectroscopy (XPS) was used to analyze the surface of electropolished stainless steel that exhibited different shades of blue, gold, and black. The near-surface Cr/Fe ratio was determined and related to corrosion resistance. The depth of the passive layer was measured for each of the colors.
This publication is a review article, summarizing the use of Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) to analyze the surface of stainless steel. The results obtained on typical "industrially clean" stainless steel are discussed. The surface chemstry of 316L stainless steel as a function of nitric acid passivation time was measured.